| 論文名 |
Quantitative emergence of hetero[4]rotaxanes by template-directed click chemistry. |
| 著者 |
Chenfeng Ke
Ronald A Smaldone
Takashi Kikuchi
Hao Li
Anthony P Davis
J Fraser Stoddart
|
| キーワード |
|
| 出版年月 |
1970年1月 |
| 発表先 |
Angew Chem Int Ed Engl. 2013 Jan 2;52(1):381-7. |
| WEBサイト |
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| 論文概要（和文） |
テンプレート指向クリックケミストリーによるヘテロ[4]ロタキサンの定量的出現。 |
| 論文概要（英文） |
In one fell swoop, polyrotaxanes comprising up to 64 rings can be synthesized as a result of cucurbit[6]uril-templated 1,3-dipolar azide-alkyne cycloadditions accelerated in the presence of cyclodextrins as a consequence of self-sorting and positive cooperativity, brought about by hydrogen bonding. Mixing six components in one pot affords a hetero[4]rotaxane in one minute in quantitative yield. |
