| 論文名 |
A membraneless glucose/O(2) biofuel cell based on Pd aerogels. |
| 著者 |
Dan Wen
Wei Liu
Anne-Kristin Herrmann
Alexander Eychm?ller
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| キーワード |
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| 出版年月 |
1970年1月 |
| 発表先 |
Chemistry. 2014 Apr 7;20(15):4380-5. doi: 10.1002/chem.201304635. Epub 2014 Feb 26. |
| WEBサイト |
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| 論文概要(和文) |
Pdエアロゲルに基づく無膜グルコース/ O(2)バイオ燃料電池 |
| 論文概要(英文) |
In this study, we introduce the first membraneless glucose/O2 biofuel cell using Pd-based aerogels as electrode materials. The bioanode was fabricated with a coimmobilized mediator and glucose oxidase for the oxidation of glucose, in which ferrocenecarboxylic acid was integrated into a three-dimensional porous beta-cyclodextrin-modified Pd aerogel to mediate the bioelectrocatalytic reaction. Bilirubin oxidase and Pd-Pt alloy aerogel were confined to an electrode surface, which realized the direct bioelectrocatalytic function for the reduction of O2 to H2 O with a synergetic effect at the biocathode. By employing these two bioelectrodes, the assembled glucose/O2 biofuel cell showed a maximum power output of 20 μW cm(-2) at 0.25 V. |