| 論文名 |
A supramolecular tubular nanoreactor. |
| 著者 |
Zhi-Qiang Li
Ying-Ming Zhang
Yong Chen
Yu Liu
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| キーワード |
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| 出版年月 |
1970年1月 |
| 発表先 |
Chemistry. 2014 Jul 7;20(28):8566-70. doi: 10.1002/chem.201402612. Epub 2014 May 30. |
| WEBサイト |
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| 論文概要(和文) |
超分子管状ナノリアクター |
| 論文概要(英文) |
The extremely strong noncovalent complexation between the rigid host of phthalocyanine-bridged β-cyclodextrins and the amphiphilic guest carboxylated porphyrin is employed to construct a hollow tubular structure as a supramolecular nanoreactor. A representative coupling reaction occurs in the hydrophobic interlayers of the tubular walls in pure water at room temperature, leading to an enhancement of ten times higher reaction rate without any adverse effect on catalytic activity and conversion. |