| 論文名 |
A metal-organic framework stabilizes an occluded photocatalyst. |
| 著者 |
Shuangbing Han
Yanhu Wei
Bartosz A Grzybowski
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| キーワード |
|
| 出版年月 |
1970年1月 |
| 発表先 |
Chemistry. 2013 Aug 19;19(34):11194-8. |
| WEBサイト |
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| 論文概要（和文） |
金属有機フレームワークは、閉塞した光触媒を安定化します。 |
| 論文概要（英文） |
Occlusion and confinement of a [Ru(bpy)3 ]Cl2 photocatalyst in the cavities of a γ-cyclodextrin (CD) metal-organic framework (MOF) does not affect the catalyst's activity but prevents its photodegradation. Additionally, the OH(-) ions and/or ROH groups present inside the CD-MOF act as electron donors and complete the catalytic cycle. The occlusion approach is a technically straightforward alternative to the covalent modification of MOF scaffolds with catalytic units. |
