| 論文名 |
Hydroformylation in aqueous biphasic media assisted by molecular receptors. |
| 著者 |
Hapiot F
Bricout H
Tilloy S
Monflier E
|
| キーワード |
|
| 出版年月 |
1970年1月 |
| 発表先 |
Top Curr Chem. 2013;342:49-78. |
| WEBサイト |
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| 論文概要（和文） |
分子受容体によって支援された水性二相媒体中のヒドロホルミル化。 |
| 論文概要（英文） |
The role of molecular receptors in aqueous biphasic hydroformylation of higher olefins is highlighted through a detailed analysis of their molecular recognition properties. The behavior of cyclodextrins and calixarenes as molecular receptors is especially emphasized and discussed. Their supramolecular interactions with the substrates and the water-soluble ligands proved to be an essential parameter guiding the reaction performances. The hydroformylation activity and chemo- and regio-selectivities can thus be accurately controlled by a suitable match between the receptor and the reaction components. Development outlooks are also presented. |
