| 論文名 |
Implementing the "catch-and-release" concept into a simple method for regioselective cyclodextrin modification. |
| 著者 |
Iris Pflueger
Juan M Benito
|
| キーワード |
|
| 出版年月 |
1970年1月 |
| 発表先 |
Org Lett. 2013 May 17;15(10):2354-7. |
| WEBサイト |
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| 論文概要（和文） |
位置選択的シクロデキストリン修飾のための単純な方法への「キャッチアンドリリース」概念の実装。 |
| 論文概要（英文） |
Differentiation of specific positions in axial-symmetrical cyclodextrins (CDs), exhibiting a dense display of identical functional groups, is challenging. A novel strategy toward this goal that exploits a solid matrix to display the complementary reagent functionalities sufficiently far from each other to prevent CDs from reacting through more than one site is reported. Using a "catch-and-release" process based on the Staudinger reaction, the utility of this concept to easily produce complex CD functionalization patterns in one pot and without any purification step is demonstrated. |
