| 論文名 |
Modulation of the thermoresponsive behavior of poly(N,N-diethylacrylamide) via cyclodextrin host/guest interactions. |
| 著者 |
Bernhard V K J Schmidt
Martin Hetzer
Helmut Ritter
Christopher Barner-Kowollik
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| キーワード |
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| 出版年月 |
1970年1月 |
| 発表先 |
Macromol Rapid Commun. 2013 Aug;34(16):1306-11. |
| WEBサイト |
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| 論文概要（和文） |
シクロデキストリンホスト/ゲスト相互作用を介したポリ（N、N-ジエチルアクリルアミド）の熱応答性挙動の変調。 |
| 論文概要（英文） |
The modulation of the cloud point of aqueous poly(N,N-diethylacrylamide) solutions via the formation of supramolecular cyclodextrin complexes with hydrophobic end groups, namely adamantyl, tert-butyl phenyl and azobenzene, synthesized via RAFT polymerization is described. The dependence of the apparent cloud points after cyclodextrin complexation is investigated with respect to the type and quantity of the guest end group, the polymer chain length and the cyclodextrin/end group ratio. Furthermore, the effect is reversed via the addition of guest molecules or via biocompatible enzymatic degradation of the cyclodextrins entire. |
