| 論文名 |
N,N'-(Hexane-1,6-diyl)bis(4-methyl-N-(oxiran-2-ylmethyl)benzenesulfonamide): Synthesis via cyclodextrin mediated N-alkylation in aqueous solution and further Prilezhaev epoxidation. |
| 著者 |
Julian Fischer
Simon Millan
Helmut Ritter
|
| キーワード |
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| 出版年月 |
1970年1月 |
| 発表先 |
Beilstein J Org Chem. 2013 Dec 9;9:2834-40. |
| WEBサイト |
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| 論文概要（和文） |
N、N '-（ヘキサン-1,6-ジイル）ビス（4-メチル-N-（オキシラン-2-イルメチル）ベンゼンスルホンアミド）：水溶液中でのシクロデキストリン媒介N-アルキル化による合成とさらなるプリレザエフエポキシ化。 |
| 論文概要（英文） |
N-alkylation of N,N'-(hexane-1,6-diyl)bis(4-methylbenzenesulfonamide) with allyl bromide and subsequent Prilezhaev reaction with m-chloroperbenzoic acid to give N,N'-(hexane-1,6-diyl)bis(4-methyl-N-(oxiran-2-ylmethyl)benzenesulfonamide) is described. This twofold alkylation was performed in aqueous solution, whereby α-, and randomly methylated β-cyclodextrin were used as adequate phase transfer catalysts and the cyclodextrin-guest complexes were characterized by (1)H NMR and 2D NMR ROESY spectroscopy. Finally, the curing properties of the diepoxide with lysine-based α-amino-ε-caprolactam were analyzed by rheological measurements. |
