| 論文名 |
Naked eye screening of 11 phenolic compounds and colorimetric determination using polydiacetylene vesicles with α-cyclodextrin. |
| 著者 |
Pimpimon Anekthirakun
Mongkol Sukwattanasinitt
Thawatchai Tuntulani
Apichat Imyim
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| キーワード |
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| 出版年月 |
1970年1月 |
| 発表先 |
Spectrochim Acta A Mol Biomol Spectrosc. 2013 Jul;111:91-6. |
| WEBサイト |
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| 論文概要（和文） |
11のフェノール化合物の裸眼スクリーニングおよびα-シクロデキストリンを含むポリジアセチレンベシクルを使用した比色定量。 |
| 論文概要（英文） |
The colorimetric response (CR) of poly(10,12-pentacosadiynoic acid) vesicles (PPCDA) induced by α-cyclodextrin (α-CD) in an aqueous solution has been studied. Various parameters affecting the CR, such as response time and concentration were investigated. The blue color of 0.01 mM PPCDA solution became pinkish red with the addition of α-CD at the concentration higher than 3 mM. The inhibition of the color transition from blue to red was investigated using 11 phenolic compounds. The color transition could be inhibited and observed by naked eye in the presence of 4 phenolic compounds, i.e. 4-nitrophenol (4-NP) and 4-bromophenol (4-BP) and 4-chlorophenol (4-CP) and 3-nitrophenol (3-NP). A colorimetric method for the determination of these compounds was validated and applied for surface water analysis. The linear range from the plot of CR against phenolic compounds concentration was in the order of 0.5-2.0 mM with R(2) more than 0.99. The recoveries were 90-95% with good precision (1-4%RSD, n=10). |
