| 論文名 |
NMR spectroscopic study of the complexation behaviors of deuterated cyclodextrins and [60]fullerene. |
| 著者 |
Atsushi Ikeda
Tomohiro Hida
Jun-ichi Kikuchi
Kazuyuki Nobusawa
Takashi Matsuo
|
| キーワード |
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| 出版年月 |
1970年1月 |
| 発表先 |
Org Lett. 2013 Dec 20;15(24):6194-7. |
| WEBサイト |
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| 論文概要(和文) |
重水素化シクロデキストリンと[60]フラーレンの錯化挙動のNMR分光研究。 |
| 論文概要(英文) |
Cyclodextrins (CDxs) have been selectively deuterated using a Ru/C-catalyzed H-D exchange reaction in D2O. The structures of the deuterated CDxs barely changed and their (1)H NMR spectra became very simple, which made it possible for the deuterated CDxs to be applied to the analysis of CDx complexes. Furthermore, the deuterated CDxs allowed for the existence of the equilibrium between free and complexed CDx to be confirmed, even at rt. |