| 論文名 |
Nonlinear amplification of a supramolecular complex at a multivalent interface. |
| 著者 |
Shu-Han Hsu
M Deniz Yilmaz
David N Reinhoudt
Aldrik H Velders
Jurriaan Huskens
|
| キーワード |
|
| 出版年月 |
1970年1月 |
| 発表先 |
Angew Chem Int Ed Engl. 2013 Jan 7;52(2):714-9. |
| WEBサイト |
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| 論文概要(和文) |
多価界面での超分子複合体の非線形増幅。 |
| 論文概要(英文) |
Competition with a monovalent cyclodextrin host (blue cones) in solution drives the multivalent binding of a Eu(3+) complex and a sensitizer molecule to cyclodextrin monolayers through a nonlinear self-assembly process. Adamantyl groups (light-blue spheres) are attached to the EDTA ligand (black) and the antenna molecule (orange), which has a carboxylate group for coordination to the Eu(3+) ion (yellow or red in free or complexed form, respectively). |