| 論文名 |
Oligomeric epoxide-amine adducts based on 2-amino-N-isopropylacetamide and α-amino-ε-caprolactam: Solubility in presence of cyclodextrin and curing properties. |
| 著者 |
Julian Fischer
Helmut Ritter
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| キーワード |
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| 出版年月 |
1970年1月 |
| 発表先 |
Beilstein J Org Chem. 2013 Dec 5;9:2803-11. |
| WEBサイト |
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| 論文概要(和文) |
2-アミノ-N-イソプロピルアセトアミドとα-アミノ-ε-カプロラクタムに基づくオリゴマーのエポキシド-アミン付加物:シクロデキストリンの存在下での溶解度と硬化特性。 |
| 論文概要(英文) |
2-Amino-N-isopropylacetamide and α-amino-ε-caprolactam were reacted with glycerol diglycidyl ether to give novel oligomeric thermoresponsive epoxide-amine adducts. These oligomers exhibit a lower critical solution temperature (LCST) behavior in water. The solubility properties were influenced with randomly methylated β-cyclodextrin (RAMEB-CD) and the curing properties of the amine-epoxide mixtures were analyzed by oscillatory rheology and differential scanning calorimetry, whereby significant differences in setting time, viscosity, and stiffness were observed. |