| 論文名 |
Per-6-amino-β-cyclodextrin as a chiral base catalyst promoting one-pot asymmetric synthesis of 2-aryl-2,3-dihydro-4-quinolones. |
| 著者 |
Kuppusamy Kanagaraj
Kasi Pitchumani
|
| キーワード |
|
| 出版年月 |
1970年1月 |
| 発表先 |
J Org Chem. 2013 Jan 18;78(2):744-51. |
| WEBサイト |
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| 論文概要（和文） |
2-アリール-2,3-ジヒドロ-4-キノロンのワンポット不斉合成を促進するキラル塩基触媒としてのペル-6-アミノ-β-シクロデキストリン。 |
| 論文概要（英文） |
A highly efficient one-pot synthesis of enantiomerically enriched 2-aryl-2,3-dihydroquinolin-4(1H)-ones has been carried out for the first time using per-6-ABCD as a supramolecular host, chiral base catalyst, and a reusable promoter to give the corresponding scaffold with high yield (up to 99%) and enantiomeric excess (up to 99%). The catalyst is recovered and reused without loss in its activity. |
