| 論文名 |
Phase-controlled supramolecular photochirogenesis in cyclodextrin nanosponges. |
| 著者 |
Wenting Liang
Cheng Yang
Dayang Zhou
Hitoshi Haneoka
Masaki Nishijima
Gaku Fukuhara
Tadashi Mori
Franca Castiglione
Andrea Mele
Fabrizio Caldera
Francesco Trotta
Yoshihisa Inoue
|
| キーワード |
|
| 出版年月 |
1970年1月 |
| 発表先 |
Chem Commun (Camb). 2013 May 4;49(34):3510-2. |
| WEBサイト |
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| 論文概要（和文） |
シクロデキストリンナノスポンジにおける位相制御超分子光合成。 |
| 論文概要（英文） |
Pyromellitate-bridged cyclodextrin nanosponges (CDNSs) evolved from sol into gel state upon gradual increase of the concentration from 0.2 to 2000 mg mL(-1) in water. The enantiodifferentiating geometrical photoisomerizations of (Z)-cyclooctene and (Z,Z)-1,3-cyclooctadiene sensitized by CDNS at various concentrations were critically affected by the phase transition of CDNS to afford the corresponding (E)- and (E,Z)-isomers in the highest enantiomeric excesses in the gel state. |
